mercury ii sulfide ionic or covalent

He claimed that the black precipitate did not show any sign of metallic mercury or cinnabar (although it was easily decomposed into them). Sulfides are the most common soft bases in geology, although the larger halides, like bromide and iodide, are also soft. The bonding characteristics of inorganic molecular compounds are different from ionic compounds, and they are named using a different system as well. that typically form only one charge, it is not usually necessary to specify Browse other questions tagged, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site. In cases like this, the charge of the metal ion is included as a Roman numeral in parentheses immediately following the metal name. Similarly, N2O is known as nitrous oxide even though our rules would specify the name dinitrogen monoxide. mercury and iodine have a fairly low electronegativity difference Write the final formula. The anion is named by taking the element Enterobactin (below) is a molecule used by certain bacteria to bind iron (III) and transport it into the cell. Hard acids interact more strongly with hard bases than they do with soft bases, and soft acids interact more strongly with soft bases than hard bases. Transition (B-group) and The simplest name, iron chloride, will, in this case, be ambiguous, as it does not distinguish between these two compounds. McGraw Hill Connect Chapter 3: Ionic Compound - Quizlet They can displace other metals from enzymes, so that the enzymes stop working. Chapter 2 Homework - Chemistry Flashcards | Quizlet The name of the more metallic element (the one farther to the left and/or bottom of the periodic table) is first, followed by the name of the more nonmetallic element (the one farther to the right and/or top) with its ending changed to the suffix ide. 2 2+ Mercury sulfide - Wikipedia = 1-exp[ -0.25(1.96-2.58)^2] = 9.16\% \ \ I.C. Use MathJax to format equations. f. (-b + (b2 - 4ac)) / 2a. PDF PRACTICE SET A--IONIC COMPOUNDS - Bellevue College [Important exception: when the compound sulfide ion, S. 2- . Metal ions are electron pair acceptors, and thus are Lewis Acids. It is represented by the chemical formula HgS. Can Martian regolith be easily melted with microwaves? These two compounds are then unambiguously named iron(II) chloride and iron(III) chloride, respectively. What did the Nazis begin using gas chambers instead of mobile killing units and shooting squads after a while. In each unit, two of the mercury atoms form SHgS bridges, while the other two form an SHgHgS bridge. Ionic bond - Electrical attraction resulting from a transfer of electrons Covalent bond - Sharing of electrons between two atoms Classify the following substances as ionic or covalent. {nZT!&Gw_cb8D9G&x"/\3y r/]She52R1v6|!G*vvXKjFM4-QDTCQwll-Re You could argue that it is. Fe(III) is a hard cation and should bind well to oxygen donors. Iron is one of the most abundant elements on earth, and many iron compounds play important roles in biology. For example, trimethylborane, Fe2+, and Pb2+ cations are intermediate acids, and pyridine and aniline are examples of intermediate bases. particles that form when an atom (or group of atoms, in the case of polyatomic Cadmium sulfide is the inorganic compound with the formula CdS. These are acids and bases with intermediate character, between hard and soft. NaHSO4. By clicking Post Your Answer, you agree to our terms of service, privacy policy and cookie policy. Do NOT use prefixes to indicate Which is a property of ionic. Percent ionic character can be estimated using equation: To subscribe to this RSS feed, copy and paste this URL into your RSS reader. The softest metal ion in the periodic table is Au+(aq). Some metals can pair with either hard or soft bases, particularly those metals from the middle of the transition metal group. hU[k0+z$J!Vv%&18Nq\X9Tv`C L %d Q+H&Hgz4r F Ni3+ (as in the layered compound NiOOH) is a hard acid, but Ni0 (as in Ni(CO)4) is a soft acid. Making statements based on opinion; back them up with references or personal experience. Quia - Ionic Compounds - Names and Formulas Manual for Chemistry 1411. one cation. a polyatomic ion with the same charge, and a similar name: Some nonmetals form a series of polyatomic ions with oxygen (all having The numbers of atoms of each element are designated by the Greek prefixes shown in Table 2.10. Iron typically exhibits a charge of either 2+ or 3+ (see Figure 2.29), and the two corresponding compound formulas are FeCl2 and FeCl3. A mass spectrometer measures neon to have two masses: 20 and 22 atomic mass units. Thus, CO is named carbon monoxide, and CO2 is called carbon dioxide. 4. by naming first the cation and then the anion. process: Molecular mass of H2O = (2 x atomic mass of H) + (1 x atomic mass of O) 1 0 obj (II) fluoride HgS mercury(II) sulfide SnO tin(II) oxide Cu 3 P copper(I) phosphide Practice 3-3 Name the following binary ionic compounds: SnS 2 PbI 2 Hg 2 O CuCl 2 FeN . Ionic Compounds Containing a Metal and a Nonmetal, Ionic Compounds Containing a Metal and a Polyatomic Iron(II) chloride or ferrous chloride Suggest which of the following bases is softer. Lithium Hydrogen Phosphate. ACD/Labs Percepta Platform - PhysChem Module, Compounds with the same molecular formula, Search Google for structures with same skeleton, Inorganic Compound; Mercury Compound; Pollutant; Industrial/Workplace Toxin; Natural Compound. What video game is Charlie playing in Poker Face S01E07? Calmodulin, which aids in calcium uptake, uses hard oxygen donors in aspartate and glutamate to bind to the Ca2+. The reaction is conveniently conducted with an acetic acid solution of mercuric acetate. Repetition is the mother of learning, they say. If so, does it also contain oxygen? is H+. 5.5_NamingandWritingIonicCompounds_Assignment.pdf - Student It is virtually insoluble in water. Celsius, which is quite low for an ionic compound (NaCl, by e. (a + b)/c(ef)-gh With the band gap of 2.1eV and its stability, it is possible to be used as photo-electrochemical cells[8], This article is about the mercuric salt. Write its formula QUESTION 9 is vanadium (11) phosphate ionic or covalent? [11][12], One may also note that the stable compound Hg4BiS2Cl5, recently synthesized, was found to consist of two-dimensional polymeric cations [(S)HgHg(SHg)Hg]2n+n balanced by one-dimensional polymeric anions [Cl(BiCl4)]2nn. Ionic bonds form instead of covalent bonds when there is a large difference in electronegativity between the ions. Many biological compounds contain iron(II), which is able to bind well to both hard and soft ligands. [15], A report from 1903 by American chemist Charles Baskerville claims that sulfuric acid left over metallic mercury in a closed bottle for over 5 years developed a crust over the metal that was found to be mercurous sulfide.[5]. It is highly soluble in polar solvents such as water, alcohol, and ammonia; slightly soluble in ether; and insoluble in benzene and other hydrophobic solvents. (-ic endings go with the higher possible and the 1411 Lab Manual, p. 27-31. (or as derived from the rules which were given). Li 3 PO 4. by covalent bonds, but that still have a net deficiency or surplus of electrons, References. The molecular mass, or molecular weight of a compound If the compound is molecular, does it contain hydrogen? Because there are three of these groups in enterobactin, and there is enough space in between for the groups to fold around a central atom, enterobactin is a chelating (hexadentate) donor with a high binding constant. If there is only one of a polyatomic ion in the formula. consent of Rice University. $X_A-X_B > 1.7$ suggests (there are deviations) that percent ionic character is greater than $50\%$ and substance can be called ionic. Lewis acids and bases can be classified by designating them as hard or soft. The covalently bonded network is three-dimensional and contains a very large number of atoms. Mercury ions, Hg(I) and Hg(II), are particularly poisonous. Compounds containing polyatomic ions are named similarly to those containing only monatomic ions, i.e. 202 0 obj <>stream The structural formula is supposed to contain two mercury atoms bound to each other, as in the real compound mercury(I) chloride (calomel), Hg2Cl2. <> the salt. Hg2 + (aq) + H 2S(aq) HgS(s) + 2H + (aq) !*$$ 6%\'an1% W*nI\qW oDwC:h0icy$puxh+|p~?( An alternative way to writing a correct formula for an ionic compound is to use the crisscross method. atoms). This book uses the endobj wbjp Indeed, many (non-academic) websites (such as this one) state that SnS is ionic. These atoms and ions tend to have high charge and/or small radius. Would tin (II) sulfide be considered a covalent network solid? Is HgI2 covalent? - Answers In naming these salts, specify the number of acidic hydrogens The settlement they won in 1996$333 millionwas the largest amount ever awarded for a direct-action lawsuit in the US at that time. Other examples are given in Table 2.13. Look at the label or ingredients list on the various products that you use during the next few days, and see if you run into any of those in this table, or find other ionic compounds that you could now name or write as a formula. View the full answer. For bases, the major hard/soft discontinuity is between the 2nd row (N,O,F) and the rows below. in parentheses by the charge written in Roman numerals. Since hydrogen is a nonmetal, binary compounds containing hydrogen are also usually covalent compounds. Suggest which of the following ions is harder. Short story taking place on a toroidal planet or moon involving flying. are not subject to the Creative Commons license and may not be reproduced without the prior and express written Cadmium sulfide is a yellow solid. be more than one of each element. sulfite), etc. This observation led to a classification system called Hard and Soft Acids and Bases (HSAB), developed by Pearson. AlN. lithium chloride aluminum sulfide (about 0.6) which gives the compound a fair amount of covalent Covalent Compounds Between Two Nonmetals, Nomenclature of Ionic and Covalent Compounds. number minus two.). These can be named as compounds as in the previous cases, e.g., HCl is Some prevalent minerals of soft metals are galena (lead sulfide, PbS2) and cinnabar (mercury sulfide, HgS). We will limit our attention here to inorganic compounds, compounds that are composed principally of elements other than carbon, and will follow the nomenclature guidelines proposed by IUPAC. [1][2], This compound was described in the 19th century by Berzelius as a black precipitate obtained by passing hydrogen sulfide H2S through solutions of mercury(I) salts. million, and still counting], the rules for naming structures more complex than Fill in the missing information in the table. Ionic Compounds Containing a Metal and a Polyatomic and you must attribute OpenStax. A. soft and flexible B. crystal lattice structure C. conducts electricity in solid and melted form D. generally, in liquid or gaseous state at room temperature. For instance: sodium hydrogen carbonate or sodium bicarbonate. points. In MO theory, it has been shown that interactions between hard anions and cations are characterized by large HOMO-LUMO separations, whereas interactions between soft anions and cations are characterized by small HOMO-LUMO separations. $$\mathrm{\% I.C. Its existence has been disputed; it may be stable below 0 C or in suitable environments, but is unstable at room temperature, decomposing into metallic mercury and mercury (II) sulfide (mercuric sulfide, cinnabar). A molecule is a compound or element containing two or more atoms joined together with covalent bonds. 183 0 obj <> endobj 3D Mercury (II) sulfide Molecular Formula HgS Average mass 232.655 Da Monoisotopic mass 233.942673 Da ChemSpider ID 56188 More details: Names Properties Searches Spectra Vendors Articles More Names and Synonyms Database ID (s) Validated by Experts, Validated by Users, Non-Validated, Removed by Users Mercury (II) sulfide [Wiki] 1344-48-5 [RN] Two nonmetals combine to form a The use of cyanide ion on a large scale in mining, however, creates a potentially serious environmental hazard. National Library of Medicine. If the compound is a binary acid (comprised of hydrogen and one other nonmetallic element): For example, when the gas HCl (hydrogen chloride) is dissolved in water, the solution is called hydrochloric acid. Cost of electric power is $0.05\$ 0.05$0.05 per kWh\mathrm{kWh}kWh. make CO (carbon monoxide), or with two oxygens to make CO2 (carbon dioxide). It only takes a minute to sign up. What is the purpose of this D-shaped ring at the base of the tongue on my hiking boots? Yes tin (ii) sulfide is covalent and that website is rittled with non-ionic bonds. (usually), Nonmetal + Nonmetal > covalent compound Boiling with potassium carbonate ("potassa", potash) removes part of the sulfur leaving pure cinnabar as residue.[6]. . The character that represents 8 the substance. The production rate for the automated machine is 555555 units per hour. Group IVA, VA, VIA, and VIIA nonmetals tend to form anions by gaining enough A metal plus a polyatomic ion Week 3: Metal-Ligand Interactions continued. { "3.2.1:_Hard_and_Soft_Acid_and_Base_Theory" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "3.2.2:_Electrostatic_Attraction" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, { "3.1_Ligands_with_more_than_one_donor_atom_(Chelating_Ligands)_have_enhanced_metal_ion_affinity" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "3.2:_The_identity_of_metal_ion_and_the_ligand_donor_atom(s)_affects_affinity" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "3.3:_Molecule_Orbital_(MO)_Theory" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, 3.2.1: Hard and Soft Acid and Base Theory, https://chem.libretexts.org/@app/auth/3/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FCourses%2FSaint_Marys_College_Notre_Dame_IN%2FCHEM_342%253A_Bio-inorganic_Chemistry%2FReadings%2FWeek_3%253A_Metal-Ligand_Interactions_continued.%2F3.2%253A_The_identity_of_metal_ion_and_the_ligand_donor_atom(s)_affects_affinity%2F3.2.1%253A_Hard_and_Soft_Acid_and_Base_Theory, \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}}}\) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\), Certain metal ions form stronger interactions with certain ligands. %PDF-1.5 % Finally, mercury also has a +1 and +2 state, so since HgO has mercury in the +2 state, and this is the higher charge, it uses the -ic suffix. Binary Furthermore, SnS dissolves in hydrochloric acid, while typical covalently bonded networks such as silicon dioxide do not. What is the purpose of non-series Shimano components? To name oxyacids: For example, consider H2CO3 (which you might be tempted to call hydrogen carbonate). Despite cleanup efforts, Cr(VI) groundwater contamination remains a problem in Hinckley and other locations across the globe. since iron can form more than one charge. Stack Exchange network consists of 181 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share their knowledge, and build their careers. nitrate, NO3-). These atoms/ions tend to have low charge and/or large radius. stem name and adding the ending -ide. Many biologically important metal ions fall under the "borderline" category between hard and soft. In the early 1990s, legal file clerk Erin Brockovich (Figure 2.32) discovered a high rate of serious illnesses in the small town of Hinckley, California. The charge on the cation is the same as Azide, which has a more polarizable, delocalized pi bonding system. [4], Mercury is produced from the cinnabar ore by roasting in air and condensing the vapour. CSID:56188, http://www.chemspider.com/Chemical-Structure.56188.html (accessed 05:04, Mar 5, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. [6], According to Scherer, Hg2S could be obtained by reaction of mercurous nitrate HgNO3 and sodium thiosulfate Na2S2O3. Writing Formulas of Ionic 3.4: Molecular and Ionic Compounds - Chemistry LibreTexts PubChem . One thing to note is that tin is a metal by a narrow margin and in fact the $\beta$-tin is non-metallic and stable below $13.6^\circ C$. The formation constant for the iron(III)-enterobactin complex is about 1049. This would be astonishing, since you would expect a metalnon-metal bond to be ionic. Finally, this paper states on the first page (which is freely accessible) that evidence for tin(II) salts with typical symmetrical ionic symmetries is completely lacking. Minimising the environmental effects of my dyson brain. National Center for Biotechnology Information. Tin (ii) sulfide is not actually soluble in hydrochloric acid, but dissolves in it much like many metals, forming tin (ii) chloride and hydrogen sulfide which are both soluble. One has to remember, though, that they are all slightly different, and all inherently arbitrary (much like the legal age limitations for driving, voting, drinking, and other activities, if we'd talk once more in terms of the "boy or man" analogy). Textbook content produced by OpenStax is licensed under a Creative Commons Attribution License . different ways to make completely different compounds. However, like cinnabar, Hg2S may be a covalent polymer [SHgHg]n rather than an ionic compound. Group IA, IIA, and IIIA metals tend to form cations by losing all of Nonmetals, Metal + Nonmetal > ionic compound (usually), Metal + Polyatomic ion > ionic compound Asking for help, clarification, or responding to other answers. cases) plus the ending -ic or -ous. endstream endobj 184 0 obj <>/Metadata 9 0 R/PageLayout/OneColumn/Pages 181 0 R/StructTreeRoot 13 0 R/Type/Catalog>> endobj 185 0 obj <>/Font<>>>/Rotate 0/StructParents 0/Type/Page>> endobj 186 0 obj <>stream In keeping with the "like binds like" principle, the compound AuI (soft-soft) is stable, but AuI3 (hard-soft) is unknown. chemistry.). It reacts with hot nitric acid yielding mercuric nitrate. Formulas of Ionic Compounds - ThoughtCo Ca(OH)2 CaOH2 ! Acids are compounds in which the "cation" Are the ions monatomic or polyatomic? Hi, Here's the solution below Rubidium dichromate Rb2Cr2O7 , It is ionic Copper (II . Chemical Formula Name Ionic or Covalent AgC 2 H 3 O 2 Silver acetate Ionic Ba(OH) 2 Barium hydroxide Ionic Ca 3 (PO 4) 2 Calcium phosphate Ionic CaCl 2 Calcium chloride Ionic Cd(NO 3) 2 Cadmium nitrate Ionic Cl 2 S 7 Dichlorine heptasulfide Covalent Co 2 O 3 Cobalt (III) oxide Ionic Co(ClO 4) 2 Cobalt (II) perchlorate Ionic electrons to fill their valence shell with eight electrons. Ionic compounds are compounds composed of ions, charged The string that represents the name Julie Nelson. (As a comparison, the molecular compound water melts at 0 C and boils at 100 C.) rev2023.3.3.43278. Other examples are provided in Table 2.9. Together, their production rate is 30 units per hour. So when we discuss hard or soft "acids" in this course, we are discussing metal ions. Transition (B-group) and George E. Shankle & Harold W. Peterson, Laboratory 2 0 obj case.) _____17. Jaime Wisniak (2016): "Nicolas-Jean-Baptiste-Gaston Guibourt". For example, consider binary ionic compounds of iron and chlorine. stream ), Ions of Some Transition Metals and Post-Transition Metals >/_D Y FhU3hDwx_f2PhIEGAdiOdap\*rWDt5|AXG( % qd# nEQ# ntW0VO"f=: 7&2 ; `T>m. within the compound. Netted solution pond next to cyanide heap leaching of gold ore near Elko, Nevada (1992). [15] However, a review of the procedure by J. T. Norton in 1900 cast doubts on the claim. the group number. The other fluoride of tin is SnF4, which was previously called stannic fluoride but is now named tin(IV) fluoride. anion. Remember to first determine whether the compound is ionic or molecular! Relatively hard potassium ions bind to oxygen atoms in DNA to help stabilize the helix structure. Hydrocarbons contain only carbon and hydrogen, and are the In his thesis he claimed that the precipitate obtained in such a manner was nothing more than an intimate mixture of mercury(II) sulfide HgS (mercuric sulfide, cinnabar) and metallic mercury Hg2, which could be separated by heating or grinding. Post-Transition (Group IVA and VA) Metals 1. The general rules for such series are summarized in the table below: The cation is written first, followed by the monatomic or polyatomic 196 0 obj <>/Filter/FlateDecode/ID[]/Index[183 20]/Info 182 0 R/Length 69/Prev 19927/Root 184 0 R/Size 203/Type/XRef/W[1 2 1]>>stream with each other. (That is, the total amount of positive charge must equal the total amount Percent ionic character can be estimated using equation: % I. C. = 1 e x p [ 0.25 ( X A X B) 2] X A X B > 1.7 suggests (there are deviations) that percent ionic character is greater than 50 % and substance can be called ionic. Hg(I) and Hg(II) are both large, polarizable ions. Who is Jason crabb mother and where is she? compound is a compound formed from two different elements. Many stable polymeric mercury compounds with the bonding system E-Hg-Hg-E (E = N, P, As, Sb, O, S, Se, and Sn) have been described since 1958. 1.7 at the least, would tin (II) sulfide be considered covalent? Alois Lecker and Arno Pfitzner (2008): "Synthese und Charakterisierung von. county ionic and covalent compounds name key university of elements compounds and mixtures bbc bitesize 7 . With gentle heating of the slurry, the black polymorph converts to the red form. These benzene rings with two OH groups next to each other are called "catechols". Chemistry Stack Exchange is a question and answer site for scientists, academics, teachers, and students in the field of chemistry. names" (especially when dissolved in water, which is most frequently the There are a lot of definitions, and it's not like they are all wrong or useless; in fact, they are necessary to keep our stuff in order. Synthese, Strukturchemie und physikalische Untersuchungen an Mangan-, Eisen- und Quecksilber-Chalkogenometallatverbindungen, https://en.wikipedia.org/w/index.php?title=Mercury(I)_sulfide&oldid=1100632031, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 26 July 2022, at 22:13. (This cannot happen with Rutherford's gold foil experiment determined that C) most of the space in an atom is empty except for a concentrated area called the nucleus. EE(CGnj-mUwKJ%}(,tE\s-{-rusHbEV)1Tk#'A~`{"t}nn>L$+hS The most common soft donor is a sulfur atom or sulfide ion; in amino acids, that suggests cysteine or methionine. When we discuss hard or soft "bases", we are discussing ligands. tin(IV)oxide copper(II)nitrate . Acids and Acid S2- sulfide Note that in some cases, the -ate form has three oxygens, and in some cases four oxygens. It is an odorless, toxic white powder. (usually), For example, iron can form two possible ions, 2+ and 3+. [6] -HgS is unreactive to all but concentrated acids. Molecular compounds are electrically neutral. a bond formed when atoms share one or more pairs of electrons Ionic bonds form between metals and nonmetals Covalent bonds are formed when two nonmetals combine, or when a metalloid bonds to a nonmetal. Note mercury (1) is not a monoatomic cation, but is really a homonuclear diatomic ion of two mercury atoms bound to each other, both having lost one electron. Li 2 CrO 4. = 1-exp[ -0.25(X_A-X_B)^2]}$$, $$\mathrm{\% I.C. Acids and bases are not strictly hard or soft, since many ions and compounds are classified as intermediate. Legal. ionic compounds, name the cation first (specifying the charge, if necessary), electrically neutral. Ronald L. Rich (2007): "Zinc through Mercury". Characteristic Reactions of Mercury Ions (Hg and Hg)

Vympel Vs Barnaul, Broken Hourglass Tattoo, Conan Exiles Cochineal Locations, Articles M